Ceramic Materials: Science and Engineering is an up-to-date treatment of ceramic science, engineering, and applications in a single, comprehensive text. Building on a foundation of crystal structures, phase equilibria, defects, and the mechanical properties of ceramic materials, students are shown how these materials are processed for a wide diversity of applications in today's society. Concepts such as how and why ions move, how ceramics interact with light and magnetic fields, and how they respond to temperature changes are discussed in the context of their applications. References to the art and history of ceramics are included throughout the text, and a chapter is devoted to ceramics as gemstones.
This course-tested text now includes expanded chapters on the role of ceramics in industry and their impact on the environment as well as a chapter devoted to applications of ceramic materials in clean energy technologies. Also new are expanded sets of text-specific homework problems and other resources for instructors. The revised and updated Second Edition is further enhanced with color illustrations throughout the text.
Ceramic Materials: Science and Engineering is an up-to-date treatment of ceramic science, engineering, and applications in a single, comprehensive text. Building on a foundation of crystal structures, phase equilibria, defects, and the mechanical properties of ceramic materials, students are shown how these materials are processed for a wide diversity of applications in today's society. Concepts such as how and why ions move, how ceramics interact with light and magnetic fields, and how they respond to temperature changes are discussed in the context of their applications. References to the art and history of ceramics are included throughout the text, and a chapter is devoted to ceramics as gemstones.
This course-tested text now includes expanded chapters on the role of ceramics in industry and their impact on the environment as well as a chapter devoted to applications of ceramic materials in clean energy technologies. Also new are expanded sets of text-specific homework problems and other resources for instructors. The revised and updated Second Edition is further enhanced with color illustrations throughout the text.
Über den Autor
Dr. Carter is the co-author of two textbooks (the other is Transmission Electron Microscopy: A Textbook for Materials Science with David Williams), co-editor of six conference proceedings, and has published more than 290 refereed journal papers and more than 400 extended abstracts/conference proceedings papers. Since 1990 he has given more than 120 invited presentations at universities, conferences and research laboratories. Among numerous awards, he has received the Simon Guggenheim Award (1985-6), the Berndt Matthias Scholar Award (1997/8) and the Alexander von Humboldt Senior Award (1997). He organized the 16th International Symposium on the Reactivity of Solids (ISRS-16 in 2007). He was an Editor of the Journal of Microscopy (1995-1999) and of Microscopy and Microanalysis (2000-2004); he continues to serve on the Editorial Board of both journals.
M. Grant Norton is Professor of Materials Science and Engineering in the School of Mechanical and Materials Engineering at Washington State University. From 2005 to 2011 he served as Associate Dean of Research and Graduate Programs in the College of Engineering and Architecture. Professor Norton obtained his PhDin Materials from Imperial College, London, in 1989,under the direction of Professor B.C.H. Steele and spent a two-year postdoctoral at Cornell University with Professor C. Barry Carter before joining the Washington State University faculty in 1991. In 2003 and 2004 he was an Air Force Office of Scientific Research (AFOSR) Faculty Research Associate at Wright-Patterson Air Force Base in Ohio and spent the 1999/2000 academic year as a Visiting Professor in the Department of Materials at Oxford University. From 2000 to 2005 Professor Norton was Chair of Materials Science at Washington State University and from 2004 to 2007 he held the Herman and Brita Lindholm Endowed Chair in Materials Science. He is author or co-author of about 200 papers in the archival literature, several bookchapters, and two textbooks.
Zusammenfassung
Integratesthe excitement of new advances in ceramics, including nanotechnology, medicineand clean energy, with fundamental concepts such as structure and defects
Explores the environmental and economic impact of ceramics on society
Describes the use of ceramics as the basis for many of today's critical technologies,including drug delivery, orthopedic implants, sensors and catalysis
Presents a comprehensive discussion on how today's ceramics are processed, fromnanotubes and thin films to bottles and toilets
Offers abundant examples and full-color illustrations relating theory topractical applications
Addresses undergraduate and graduate teaching needs and provides a comprehensivereference for all scientists and engineers
Written by established and successful teachers and authors with experience in education,research and industry
Inhaltsverzeichnis
Preface to the First EditionPreface to the Second EditionForewordPART I: History and IntroductionChapter 1: Introduction1.1 Definitions1.2 General Properties1.3 Types of Ceramic and their Applications1.4 Market1.5 Critical Issues for the Future1.6 Relating Microstructure, Processing and Applications1.7 Safety1.8 Ceramics on the Internet1.9 On UnitsChapter 2: Some History2.1 Earliest Ceramics: the Stone Age2.2 Ceramics in Ancient Civilizations2.3 Clay2.4 Types of Pottery2.5 Glazes2.6 Development of a Ceramics Industry2.7 Plaster and Cement2.8 Brief History of Glass2.9 Brief History of Refractories2.10 Major Landmarks of the 20th Century2.11 Museums2.12 Societies2.13 Ceramic EducationPART II: MaterialsChapter 3: Background You Need to Know3.1 The Atom3.2 Energy Levels3.3 Electron Waves3.4 Quantum Numbers3.5 Assigning Quantum Numbers3.6 Ions3.7 Electronegativity3.8 Thermodynamics: the Driving Force for Change3.9 Kinetics: the Speed of ChangeChapter 4: Bonds and Energy Bands4.1 Types of Interatomic Bond4.2 Youngs Modulus4.3 Ionic Bonding4.4 Covalent Bonding4.5 Metallic Bonding in Ceramics4.6 Mixed Bonding4.7 Secondary Bonding4.8 Electron Energy BandsChapter 5: Models, Crystals and Chemistry5.1 Terms and Definitions5.2 Symmetry and Crystallography5.3 Lattice Points, Directions and Planes5.4 The Importance of Crystallography5.5 Paulings Rules5.6 Close-Packed Arrangements: Interstitial Sites5.7 Notation for Crystal Structures5.8 Structure, Composition and Temperature5.9 Crystals, Glass, Solids and Liquid5.10 Defects5.11 Computer ModelingChapter 6: Binary Compounds6.1 Background6.2 CsCl6.3 NaCl (MgO, TiC, PbS) 6.4 GaAs (ß-SiC) 6.5 AlN (BeO, ZnO) 6.6 CaF26.7 FeS26.8 Cu2O6.9 CuO6.10 TiO26.11 Al2O36.12 MoS2 and CdI26.13 Polymorphs, Polytypes and PolytypoidsChapter 7: Complex Crystal and Glass Structures7.1 Introduction7.2 Spinel7.3 Perovskite7.4 The Silicates and Structures Based on SiO47.5 Silica7.6 Olivine7.7 Garnets7.8 Ring Silicates7.9 Micas and Other Layer Materials7.10 Clay Minerals7.11 Pyroxene7.12 ß-Aluminas and Related Materials7.13 Calcium Aluminate and Related Materials7.14 Mullite7.15 Monazite7.16 YBa2Cu3O7 and Related HTSCs7.17 Si3N4, SiAlONs and Related Materials7.18 Fullerenes and Nanotubes7.19 Zeolites and Microporous Compounds7.20 Zachariasens Rules for the Structure of Glass7.21 Revisiting Glass StructuresChapter 8: Equilibrium Phase Diagrams8.1 Whats Special About Ceramics? 8.2 Determining Phase Diagrams8.3 Phase Diagrams for Ceramists: The Books8.4 Gibbs Phase Rule8.5 One Component (C = 1) 8.6 Two Components (C = 2) 8.7 Three and More Components8.8 Composition with Variable Oxygen Partial Pressure8.9 Ternary Diagrams and Temperature8.10 Congruent and Incongruent Melting8.11 Miscibility Gaps in GlassPART III: ToolsChapter 9: Furnaces9.1 The Need for High Temperatures9.2 Types of Furnace9.3 Combustion Furnaces9.4 Electrically Heated Furnaces9.5 Batch or Continuous Operation9.6 Indirect Heating9.7 Heating Elements9.8 Refractories9.9 Furniture, Tubes and Crucibles9.10 Firing Process9.11 Heat Transfer9.12 Measuring Temperature9.13 SafetyChapter 10: Characterizing Structure, Defects and Chemistry10.1 Characterizing Ceramics10.2 Imaging using Visible-Light, IR and UV10.3 Imaging using X-rays and CT scans10.4 Imaging in the SEM10.5 Imaging in the TEM10.6 Scanning-Probe Microscopy10.7 Scattering and Diffraction Techniques10.8. Photon Scattering10.9 Raman and IR Spectroscopy10.10 NMR Spectroscopy and Spectrometry10.11 Mössbauer Spectroscopy and Spectrometry10.12 Diffraction in the EM10.13 Ion Scattering (RBS) 10.14 X-ray Diffraction and Databases10.15 Neutron Scattering10.16 Mass Spectrometry10.17 Spectrometry in the EM10.18 Electron Spectroscopy10.19 Neutron Activation Analysis (NAA) 10.20 Thermal AnalysisPART IV: DefectsChapter 11: Point Defects, Charge and Diffusion11.1 Are Defects in Ceramics Different? 11.2 Types of Point Defects11.3 What is Special for Ceramics? 11.4 What Type of Defects Form? 11.5 Equilibrium Defect Concentrations11.6 Writing Equations for Point Defects11.7 Solid Solutions11.8 Association of Point Defects11.9 Color Centers11.10 Creation of Point Defects in Ceramics11.11 Experimental Studies of Point Defects11.12 Diffusion11.13 Diffusion in Impure, or Doped, Ceramics11.14 Movement of defects11.15 Diffusion and Ionic Conductivity11.16 ComputingChapter 12: Are Dislocations Unimportant?12.1 A Quick Review of Dislocations12.2 Summary of Dislocation Properties12.3 Observation of Dislocations12.4 Dislocations in Ceramics12.5 Structure of the Core12.6 Detailed Geometry12.7 Defects on Dislocations12.8 Dislocations and Diffusion12.9 Movement of Dislocations12.10 Multiplication of Dislocations12.11 Dislocation Interactions12.12 At the Surface12.13 Indentation, Scratching and Cracks12.14 Dislocations with Different CoresChapter 13: Surfaces, Nanoparticles and Foams13.1 Background to surfaces13.2 Ceramic Surfaces13.3 Surface Energy13.4 Surface structure13.5 Curved Surfaces and Pressure13.6 Capillarity13.7 Wetting and Dewetting13.8 Foams13.9 Epitaxy and Film Growth13.10 Film Growth in 2D: Nucleation13.11 Film Growth in 2D: Mechanisms13.12 Characterizing Surfaces13.13 Steps13.14 In situ13.15 Surfaces and Nano13.16 Computer modeling13.17 Introduction to propertiesChapter 14: Interfaces in Polycrystals14.1 What are Grain Boundaries? 14.2 For Ceramics14.3 GB Energy14.4 Low-angle GBs14.5 High-angle GBs14.6 Twin Boundaries14.7 General Boundaries14.8 GB Films14.9 Triple Junctions and GB Grooves14.10 Characterizing GBs14.11 GBs in Thin Films14.12 Space Charge and Charged Boundaries14.13 Modeling14.14 Some PropertiesChapter 15: Phase Boundaries, Particles and Pores15.1 The importance15.2 Different types15.3 Compare to other materials15.4 Energy15.5 The structure of PBs15.6 Particles15.7 Use of particles15.8 Nucleation and growth of particles15.9 Pores15.10 Measuring porosity15.11 Porous ceramics15.12 Glass/crystal phase boundaries15.13 Eutectics15.14 Metal/ceramic PBs15.15 Forming PBs by joiningPART V: Mechanical Strength and WeaknessChapter 16: Mechanical Testing16.1 Philosophy16.2 Types of testing16.3 Elastic Constants and Other `Constants16.4. Effect of Microstructure on Elastic Moduli16.5. Test Temperature16.6. Test Environment16.7 Testing in Compression and Tension16.8 Three- and Four-point Bending16.9 KIc from Bend Test16.10 Indentation16.11 Fracture Toughness From Indentation16.12 Nanoindentation16.13 Ultrasonic Testing16.14 Design and Statistics16.15 SPT DiagramsChapter 17: Plasticity17.1 Plastic Deformation17.2 Dislocation Glide17.3 Slip in Alumina17.4 Plastic Deformation in single crystals17.5 Plastic Deformation in Polycrystals17.6 Dislocation Velocity and Pinning17.7 Creep17.8 Dislocation Creep17.9 Diffusion-Controlled Creep17.10 Grain-Boundary Sliding17.11 Tertiary Creep and Cavitation17.12 Creep Deformation Maps17.13 Viscous Flow17.14 SuperplasticityChapter 18: Fracturing: Brittleness18.1 The importance of brittleness18.2 Theoretical StrengthThe Orowan Equation18.3 The Effect of Flawsthe Griffith Equation18.4 The Crack TipThe Inglis Equation18.5 Stress Intensity Factor18.6 R Curves18.7 Fatigue and Stress Corrosion Cracking18.8 Failure and Fractography18.9 Toughening and Ceramic Matrix Composites18.10 Machinable Glass-Ceramics18.11 Wear18.12 Grinding and polishingPART VI: ProcessingChapter 19: Raw Materials19.1 Geology, Minerals, and Ores19.2 Mineral Formation19.3 Beneficiation19.4 Weights and Measures19.5 Silica19.6 Silicates19.7 Oxides19.8 Non OxidesChapter 20: Powders, Fibers, Platelets and Composites20.1 Making Powders20.2. Types of powders20.3 Mechanical Milling20.4 Spray Drying20.5 Powders by Sol-gel Processing20.6 Powders by Precipitation20.7 Chemical Routes to Non-oxide powders20.8 Platelets20.9 Nanopowders by Vapor-Phase reactions20.10 Characterizing Powders20.11 Characterizing Powders by Microscopy20.12 Sieving20.13 Sedimentation20.14 The Coulter counter20.15 Characterizing Powders by Light Scattering20.16 Characterizing Powders by X-Ray Diffraction20.17 Measuring Surface Area (The BET method) 20.18 Determining Particle composition and purity20.19 Making Fibers and whiskers20.20 Oxide fibers20.21 Whiskers20.22 Glass fibers20.23 Coating Fibers20.24 Making CMCs20.25 CMCs From Powders and slurries20.26 CMCs By Infiltration20.27 In-situ processesChapter 21: Glass and Glass-Ceramics21.1 Definitions21.2 History21.3 Viscosity, 21.4 GlassA Summary of its Properties, or not21.5 Defects in Glass21.6 Heterogeneous Glass21.7 YA glass21.8 Coloring Glass21.9 Glass laser21.10 Precipitates in Glass21.11 Crystallizing Glass21.12 Glass as Glaze and Enamel21.13 Corrosion of Glass and Glaze21.14 Types of Ceramic Glasses21.15 Natural glass21.16 The Physics of GlassChapter 22: Sols, Gels and Organic Chemistry22.1 Sol-gel processing22.2 Structure and synthesis of alkoxides22.3 Properties of alkoxides22.4 The sol-gel process using metal alkoxides22.5 Characterization of the sol-gel Process22.6 Powders, coatings, fibers, crystalline or glass? Chapter 23: Shaping and Forming23.1 The Words23.2 Binders and Plasticizers23.3 Slip and Slurry23.4 Dry Pressing23.5 Hot Pressing23.6 Cold Isostatic Pressing23.7 Hot Isostatic Pressing23.8 Slip Casting23.9 Extrusion23.10 Injection molding23.11 Rapid prototyping23.12 Green machining23.13 Binder burnout23.14 Final machining23.15 Making Porous Ceramics23.16 Shaping Pottery23.17 Shaping GlassChapter 24: Sintering and Grain Growth24.1 The sintering process24.2 The terminology of sintering24.3 Capillary forces and Surface Forces24.4 Sintering spheres and wires24.5 Grain growth24.6 Sintering and Diffusion24.7 LPS24.8 Hot pressing24.9 Pinning Grain Boundaries24.10 Grain Growth24.11 Grain boundaries, surfaces and sintering24.12 Exaggerated grain growth24.13 Fabricating complex shapes24.14 Pottery24.15 Pores and Porous Ceramics24.16 Sintering with 2- and 3-phases24.17 Examples of sintering in action24.18 Computer ModelingChapter 25: Solid-State Phase Transformations &...